Continuous flow hydrogenation using polysilane-supported palladium/alumina hybrid catalysts
نویسندگان
چکیده
Continuous flow systems for hydrogenation using polysilane-supported palladium/alumina (Pd/(PSi-Al(2)O(3))) hybrid catalysts were developed. Our original Pd/(PSi-Al(2)O(3)) catalysts were used successfully in these systems and the hydrogenation of unsaturated C-C bonds and a nitro group, deprotection of a carbobenzyloxy (Cbz) group, and a dehalogenation reaction proceeded smoothly. The catalyst retained high activity for at least 8 h under neat conditions.
منابع مشابه
Selective Hydrogenation of Nitriles to Primary Amines Catalyzed by a Polysilane/SiO2‐Supported Palladium Catalyst under Continuous‐Flow Conditions
Hydrogenation of nitriles to primary amines with heterogeneous catalysts under liquid-phase continuous-flow conditions is described. Newly developed polysilane/SiO2-supported Pd was found to be an effective catalyst and various nitriles were converted into primary amine salts in almost quantitative yields under mild reaction conditions. Interestingly, a complex mixture was obtained under batch ...
متن کاملPolysilane-supported Pd and Pt nanoparticles as efficient catalysts for organic synthesis.
Polysilane-supported Pd and Pt catalysts have been prepared for the first time, and used successfully in hydrogenation, Suzuki and Sonogashira reactions, and hydrosilylation respectively: the reactions proceeded in high yields, and the catalysts could be recovered almost quantitatively by simple filtration and reused.
متن کاملMorphological and chemical influences on alumina-supported palladium catalysts active for the gas phase hydrogenation of crotonaldehyde.
A series of five alumina-supported palladium catalysts have previously been prepared and characterised by a combination of CO chemisorption and infrared spectroscopy. The reactive attributes of these catalysts are examined using the hydrogenation of crotonaldehyde as a test reaction, using a modified infrared gas cell as a batch reactor. Periodic scanning of the infrared spectrum of the gaseous...
متن کاملSupport Effects on Palladium Catalysts for Methanol Fuel Applications
Methanol, formaldehyde, carbon monoxide, and propylene conversion were examined in a laboratory flow reactor over three base-metal containing alumina-supported palladium (Pd) catalysts in addition to Pd on y-alumina catalyst. The base metals were cerium, barium, and a combination of the two. Experiments were performed to determine the effect of air to fuel ratio on lightoff temperatures of vari...
متن کاملChemoselective hydrogenation of cinnamaldehyde at atmospheric pressure over combustion synthesized Pd catalysts
A series of Pd-supported metal oxides (Al2O3, Fe2O3 and CeO2) have been prepared by a single step solution combustion synthesis (SCS). Their catalytic performance was evaluated for selective hydrogenation of cinnamaldehyde (CAL) to hydrocinnamaldehyde (HCAL) under atmospheric pressure of hydrogen at 100 °C. Among these materials, combustion synthesized Pd (2 at.%)/Al2O3 catalyst exhibits the hi...
متن کامل